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When the centre of a molecule is orientated so that the lowest priority of four ligands is pointed away from the viewer, the centre is labelled R if ligands of decreasing priority are arranged in a clockwise orientation, or S if this arrangement is anticlockwise

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[14] Small clinical trials indicate that maternal supplementation of 4,000 IU day ⁻¹ or staggered 50,000 IU oral doses can safely maintain 25-hydroxyvitamin D above 30 ng mL ⁻¹ without inducing hypercalcaemia, whereas single injections of 300,000 IU are reserved for severe malabsorption emergencies when benefits outweigh theoretical teratogenic risk